Synthesis and spectral investigations of covalently linked phthalocyanine-c60 dyad via flexible carbon linker

Daisuke Sukeguchi; Hideyuki Yoshiyama; Surya Prakash Singh; Norio Shibata; Shuichi Nakamura; Takeshi Toru; Yasuhiko Hayashi; Tetsuo Soga

doi:10.1515/HC.2009.15.4.263

Synthesis and spectral investigations of covalently linked phthalocyanine-c₆₀ dyad via flexible carbon linker

Daisuke Sukeguchi, Hideyuki Yoshiyama, Surya Prakash Singh, Norio Shibata, Shuichi Nakamura, Takeshi Toru, Yasuhiko Hayashi, Tetsuo Soga

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Phthalocyanine-C₆₀ dyad 1 via a flexible saturated carbon linker was synthesized. The UV/Vis and fluorescence spectra studies of 1 revealed that intramolecular, not intermolecular, photoinduced electronic communication was observed in the solution state. We also examined UV-Vis and fluorescence spectra of a mixture of C₆₀ and conventional tetra tert-Bu phthalocyanine 2 for comparison.

Original language	English
Pages (from-to)	263-272
Number of pages	10
Journal	Heterocyclic Communications
Volume	15
Issue number	4
DOIs	https://doi.org/10.1515/HC.2009.15.4.263
Publication status	Published - 2009
Externally published	Yes

Keywords

Flexible carbon linker, electronic communication
Fullerene
Hybrid molecule
Phthalocyanine

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1515/HC.2009.15.4.263

Cite this

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title = "Synthesis and spectral investigations of covalently linked phthalocyanine-c60 dyad via flexible carbon linker",

abstract = "Phthalocyanine-C60 dyad 1 via a flexible saturated carbon linker was synthesized. The UV/Vis and fluorescence spectra studies of 1 revealed that intramolecular, not intermolecular, photoinduced electronic communication was observed in the solution state. We also examined UV-Vis and fluorescence spectra of a mixture of C60 and conventional tetra tert-Bu phthalocyanine 2 for comparison.",

keywords = "Flexible carbon linker, electronic communication, Fullerene, Hybrid molecule, Phthalocyanine",

author = "Daisuke Sukeguchi and Hideyuki Yoshiyama and Singh, {Surya Prakash} and Norio Shibata and Shuichi Nakamura and Takeshi Toru and Yasuhiko Hayashi and Tetsuo Soga",

year = "2009",

doi = "10.1515/HC.2009.15.4.263",

language = "English",

volume = "15",

pages = "263--272",

journal = "Heterocyclic Communications",

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T1 - Synthesis and spectral investigations of covalently linked phthalocyanine-c60 dyad via flexible carbon linker

AU - Sukeguchi, Daisuke

AU - Yoshiyama, Hideyuki

AU - Singh, Surya Prakash

AU - Shibata, Norio

AU - Nakamura, Shuichi

AU - Toru, Takeshi

AU - Hayashi, Yasuhiko

AU - Soga, Tetsuo

PY - 2009

Y1 - 2009

N2 - Phthalocyanine-C60 dyad 1 via a flexible saturated carbon linker was synthesized. The UV/Vis and fluorescence spectra studies of 1 revealed that intramolecular, not intermolecular, photoinduced electronic communication was observed in the solution state. We also examined UV-Vis and fluorescence spectra of a mixture of C60 and conventional tetra tert-Bu phthalocyanine 2 for comparison.

AB - Phthalocyanine-C60 dyad 1 via a flexible saturated carbon linker was synthesized. The UV/Vis and fluorescence spectra studies of 1 revealed that intramolecular, not intermolecular, photoinduced electronic communication was observed in the solution state. We also examined UV-Vis and fluorescence spectra of a mixture of C60 and conventional tetra tert-Bu phthalocyanine 2 for comparison.

KW - Flexible carbon linker, electronic communication

KW - Fullerene

KW - Hybrid molecule

KW - Phthalocyanine

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