Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

Yutaka Takaguchi; Naomichi Furukawa

doi:10.1246/cl.1996.365

Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

Yutaka Takaguchi, Naomichi Furukawa

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

Original language	English
Pages (from-to)	365-366
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.1996.365
Publication status	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride. / Takaguchi, Yutaka; Furukawa, Naomichi.
In: Chemistry Letters, No. 5, 1996, p. 365-366.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride",

abstract = "Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.",

author = "Yutaka Takaguchi and Naomichi Furukawa",

year = "1996",

doi = "10.1246/cl.1996.365",

language = "English",

pages = "365--366",

journal = "Chemistry Letters",

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T2 - Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

AU - Takaguchi, Yutaka

AU - Furukawa, Naomichi

PY - 1996

Y1 - 1996

N2 - Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

AB - Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

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Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

Abstract

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