Synthesis of (+)-Homononactic Acid via Iodoetherification

Hiromasa Kiyota; Masaki Abe; Yukie Ono; Takayuki Oritani

doi:10.1055/s-1997-1547

Synthesis of (+)-Homononactic Acid via Iodoetherification

Hiromasa Kiyota, Masaki Abe, Yukie Ono, Takayuki Oritani

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

(+)-Homononactic acid, one of the monomers of polynactin, and its 8-epimer were synthesized. The key step was cis-selective iodoetherification of the enone or the α-silyloxyolefin intermediates constructed with Wittig-Horner or Julia coupling reactions, respectively.

Original language	English
Pages (from-to)	1093-1095
Number of pages	3
Journal	Synlett
Volume	1997
Issue number	9
DOIs	https://doi.org/10.1055/s-1997-1547
Publication status	Published - Jan 1 1997
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Synthesis of (+)-Homononactic Acid via Iodoetherification",

abstract = "(+)-Homononactic acid, one of the monomers of polynactin, and its 8-epimer were synthesized. The key step was cis-selective iodoetherification of the enone or the α-silyloxyolefin intermediates constructed with Wittig-Horner or Julia coupling reactions, respectively.",

author = "Hiromasa Kiyota and Masaki Abe and Yukie Ono and Takayuki Oritani",

year = "1997",

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doi = "10.1055/s-1997-1547",

language = "English",

volume = "1997",

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journal = "Synlett",

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T1 - Synthesis of (+)-Homononactic Acid via Iodoetherification

AU - Kiyota, Hiromasa

AU - Abe, Masaki

AU - Ono, Yukie

AU - Oritani, Takayuki

PY - 1997/1/1

Y1 - 1997/1/1

N2 - (+)-Homononactic acid, one of the monomers of polynactin, and its 8-epimer were synthesized. The key step was cis-selective iodoetherification of the enone or the α-silyloxyolefin intermediates constructed with Wittig-Horner or Julia coupling reactions, respectively.

AB - (+)-Homononactic acid, one of the monomers of polynactin, and its 8-epimer were synthesized. The key step was cis-selective iodoetherification of the enone or the α-silyloxyolefin intermediates constructed with Wittig-Horner or Julia coupling reactions, respectively.

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U2 - 10.1055/s-1997-1547

DO - 10.1055/s-1997-1547

M3 - Article

AN - SCOPUS:0001303122

SN - 0936-5214

VL - 1997

SP - 1093

EP - 1095

JO - Synlett

JF - Synlett

IS - 9

ER -

Synthesis of (+)-Homononactic Acid via Iodoetherification

Abstract

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