Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V

Hiroki Asao; Yasuharu Shimasaki; Ayaka Sasaki; Shunki Katayama; Kousuke Ida; Masaaki Kotake; Eriko Sato; Yuki Sato; Taiki Ishimoto; Minoru Izumi; Christopher J. Vavricka; Shigefumi Kuwahara; Hiromasa Kiyota

doi:10.1093/bbb/zbae049

Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V

Hiroki Asao
, Yasuharu Shimasaki
, Ayaka Sasaki
, Shunki Katayama
, Kousuke Ida
, Masaaki Kotake
, Eriko Sato
, Yuki Sato
, Taiki Ishimoto
, Minoru Izumi
, Christopher J. Vavricka
, Shigefumi Kuwahara
, Hiromasa Kiyota

Research output: Contribution to journal › Article › peer-review

Abstract

Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic αmethylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.

Original language	English
Pages (from-to)	733-741
Number of pages	9
Journal	Bioscience, Biotechnology and Biochemistry
Volume	88
Issue number	7
DOIs	https://doi.org/10.1093/bbb/zbae049
Publication status	Published - Jul 1 2024

Keywords

Diels-Alder reaction
intramolecular aldol reaction
maoecrystal V
synthesis

ASJC Scopus subject areas

Analytical Chemistry
Biotechnology
Biochemistry
Applied Microbiology and Biotechnology
Molecular Biology
Organic Chemistry

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10.1093/bbb/zbae049

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title = "Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V",

abstract = "Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic αmethylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.",

keywords = "Diels-Alder reaction, intramolecular aldol reaction, maoecrystal V, synthesis",

author = "Hiroki Asao and Yasuharu Shimasaki and Ayaka Sasaki and Shunki Katayama and Kousuke Ida and Masaaki Kotake and Eriko Sato and Yuki Sato and Taiki Ishimoto and Minoru Izumi and Vavricka, \{Christopher J.\} and Shigefumi Kuwahara and Hiromasa Kiyota",

note = "Publisher Copyright: {\textcopyright} The Author(s) 2024. Published by Oxford University Press on behalf of Japan Society for Bioscience, Biotechnology, and Agrochemistry. All rights reserved.",

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doi = "10.1093/bbb/zbae049",

language = "English",

volume = "88",

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T1 - Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V

AU - Asao, Hiroki

AU - Shimasaki, Yasuharu

AU - Sasaki, Ayaka

AU - Katayama, Shunki

AU - Ida, Kousuke

AU - Kotake, Masaaki

AU - Sato, Eriko

AU - Sato, Yuki

AU - Ishimoto, Taiki

AU - Izumi, Minoru

AU - Vavricka, Christopher J.

AU - Kuwahara, Shigefumi

AU - Kiyota, Hiromasa

PY - 2024/7/1

Y1 - 2024/7/1

N2 - Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic αmethylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.

AB - Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic αmethylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.

KW - Diels-Alder reaction

KW - intramolecular aldol reaction

KW - maoecrystal V

KW - synthesis

UR - https://www.scopus.com/pages/publications/85196918816

UR - https://www.scopus.com/pages/publications/85196918816#tab=citedBy

U2 - 10.1093/bbb/zbae049

DO - 10.1093/bbb/zbae049

M3 - Article

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AN - SCOPUS:85196918816

SN - 0916-8451

VL - 88

SP - 733

EP - 741

JO - Bioscience, Biotechnology and Biochemistry

JF - Bioscience, Biotechnology and Biochemistry

IS - 7

ER -

Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V

Abstract

Keywords

ASJC Scopus subject areas

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