@article{740ca0e79e1f4e05aa7c4bd21f6be863,
title = "Synthesis of γ-Boryl-Substituted Homoallylic Alcohols with anti Stereochemistry Based on a Double-Bond Transposition",
abstract = "The stereoselective synthesis of anti isomers of γ-boryl-substituted homoallylic alcohols is disclosed. (E)-1,2-Di(boryl)alk-1-enes undergo Ru-catalyzed double-bond transposition with control of the geometry. The in situ generated (E)-1,2-di(boryl)alk-2-enes add to aldehydes in a stereospecific manner. The alkenylboron group within the product is amenable to a variety of synthetic derivatizations.",
keywords = "allylation, allylic compounds, boron, ruthenium, stereoselective synthesis",
author = "Tomoya Miura and Junki Nakahashi and Takanori Sasatsu and Masahiro Murakami",
note = "Funding Information: We thank Dr. N. Ishida (Kyoto University) for his kind help with the computational studies and Prof. S. G. Stewart (The University of Western Australia) for his assistance with experiments. This work was supported by JSPS KAKENHI [Scientific Research (S) (15H05756) and (C) (16K05694)] and JST [ACT-C (JPMJCR12Z9)]. J.N. thanks the JSPS for Young Scientists for a Research Fellowship. Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2019",
month = jan,
day = "21",
doi = "10.1002/anie.201811205",
language = "English",
volume = "58",
pages = "1138--1142",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "4",
}