TY - JOUR
T1 - Synthesis, structure, and magnetic property of a new mononuclear iron(II) spin crossover complex with a tripodal ligand containing three 1,2,3-triazole groups
AU - Hagiwara, Hiroaki
AU - Minoura, Ryo
AU - Okada, Shohei
AU - Sunatsuki, Yukinari
PY - 2014
Y1 - 2014
N2 - A novel mononuclear iron(II) complex of a 1,2,3-triazolecontaining ligand, [FeIILPh](NTf2)2 [LPh: tris(2-{[(1-phenyl- 1,2,3-triazol-4-yl)methylidene]amino}ethyl)amine and NTf2: bis(trifluoromethanesulfonyl)imide], was synthesized. The complex shows a gradual one-step spin crossover at around room temperature with T1/2 = 280 K. The complex cations, [FeIIL Ph]2+, are linked via CH/π and ππ interactions forming a two-dimensional layer. The cationic layers are linked together by NTf2- ions via CH·X (X= N, O, and F) hydrogen-bonding interactions to form an extended three-dimensional structure.
AB - A novel mononuclear iron(II) complex of a 1,2,3-triazolecontaining ligand, [FeIILPh](NTf2)2 [LPh: tris(2-{[(1-phenyl- 1,2,3-triazol-4-yl)methylidene]amino}ethyl)amine and NTf2: bis(trifluoromethanesulfonyl)imide], was synthesized. The complex shows a gradual one-step spin crossover at around room temperature with T1/2 = 280 K. The complex cations, [FeIIL Ph]2+, are linked via CH/π and ππ interactions forming a two-dimensional layer. The cationic layers are linked together by NTf2- ions via CH·X (X= N, O, and F) hydrogen-bonding interactions to form an extended three-dimensional structure.
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U2 - 10.1246/cl.140133
DO - 10.1246/cl.140133
M3 - Article
AN - SCOPUS:84901919996
SN - 0366-7022
VL - 43
SP - 950
EP - 952
JO - Chemistry Letters
JF - Chemistry Letters
IS - 6
ER -