TY - JOUR
T1 - Synthetic studies towards optically active 13-oxyingenol via asymmetric cyclopropanation
AU - Hayakawa, Ichiro
AU - Miyazawa, Yamato
AU - Ohyoshi, Takayuki
AU - Asuma, Yuki
AU - Aoki, Kenta
AU - Kigoshi, Hideo
PY - 2011
Y1 - 2011
N2 - The enantioselective synthesis of a seven-membered enone compound, the key intermediate of our previous synthesis of the inside-outside framework of 13-oxyingenol in racemic form, was achieved by using asymmetric cyclopropanation and reductive deoxygenation as key steps.
AB - The enantioselective synthesis of a seven-membered enone compound, the key intermediate of our previous synthesis of the inside-outside framework of 13-oxyingenol in racemic form, was achieved by using asymmetric cyclopropanation and reductive deoxygenation as key steps.
KW - 13-oxyingenol
KW - asymmetric cyclopropanation
KW - chiral aza-semicorrin ligand
KW - intramolecular -aldol reaction
KW - reductive deoxygenation
UR - http://www.scopus.com/inward/record.url?scp=79951855626&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79951855626&partnerID=8YFLogxK
U2 - 10.1055/s-0030-1259430
DO - 10.1055/s-0030-1259430
M3 - Article
AN - SCOPUS:79951855626
SN - 0039-7881
SP - 769
EP - 777
JO - Synthesis
JF - Synthesis
IS - 5
ER -