TY - JOUR
T1 - TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes
AU - Mori, Atsunori
AU - Fujita, Akinori
AU - Ikegashira, Kazutaka
AU - Nishihara, Yasushi
AU - Hiyama, Tamejiro
PY - 1997/1/1
Y1 - 1997/1/1
N2 - The fluoride reagents, TBAH2F3 and TBAHF2 (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF2 and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.
AB - The fluoride reagents, TBAH2F3 and TBAHF2 (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF2 and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.
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U2 - 10.1055/s-1997-3276
DO - 10.1055/s-1997-3276
M3 - Article
AN - SCOPUS:0000901365
SN - 0936-5214
VL - 1997
SP - 693
EP - 694
JO - Synlett
JF - Synlett
IS - 6
ER -