Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

Manabu Kuroboshi; Muneaki Tanaka; Suguru Kishimoto; Kentaro Goto; Misato Mochizuki; Hideo Tanaka

doi:10.1016/S0040-4039(99)02006-7

Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

Manabu Kuroboshi, Muneaki Tanaka, Suguru Kishimoto, Kentaro Goto, Misato Mochizuki, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Tetrakis(dimethylamino)ethylene (TDAE) was found to be a potent organic electron source which could promote alkenylation of several kinds of aldehydes in the presence of a catalytic amount of NiBr₂ and CrCl₃.

Original language	English
Pages (from-to)	81-84
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	1
DOIs	https://doi.org/10.1016/S0040-4039(99)02006-7
Publication status	Published - Jan 1 2000

Keywords

Aldehydes
Alkenylation
Enamines
Reduction

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(99)02006-7

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title = "Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system",

abstract = "Tetrakis(dimethylamino)ethylene (TDAE) was found to be a potent organic electron source which could promote alkenylation of several kinds of aldehydes in the presence of a catalytic amount of NiBr2 and CrCl3.",

keywords = "Aldehydes, Alkenylation, Enamines, Reduction",

author = "Manabu Kuroboshi and Muneaki Tanaka and Suguru Kishimoto and Kentaro Goto and Misato Mochizuki and Hideo Tanaka",

note = "Funding Information: This work was supported in part by the Ministry of Education, Science and Culture, Japan.",

year = "2000",

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doi = "10.1016/S0040-4039(99)02006-7",

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T1 - Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source

T2 - Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

AU - Kuroboshi, Manabu

AU - Tanaka, Muneaki

AU - Kishimoto, Suguru

AU - Goto, Kentaro

AU - Mochizuki, Misato

AU - Tanaka, Hideo

N1 - Funding Information: This work was supported in part by the Ministry of Education, Science and Culture, Japan.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Tetrakis(dimethylamino)ethylene (TDAE) was found to be a potent organic electron source which could promote alkenylation of several kinds of aldehydes in the presence of a catalytic amount of NiBr2 and CrCl3.

AB - Tetrakis(dimethylamino)ethylene (TDAE) was found to be a potent organic electron source which could promote alkenylation of several kinds of aldehydes in the presence of a catalytic amount of NiBr2 and CrCl3.

KW - Aldehydes

KW - Alkenylation

KW - Enamines

KW - Reduction

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U2 - 10.1016/S0040-4039(99)02006-7

DO - 10.1016/S0040-4039(99)02006-7

M3 - Article

AN - SCOPUS:0033992259

SN - 0040-4039

VL - 41

SP - 81

EP - 84

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 1

ER -

Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

Abstract

Keywords

ASJC Scopus subject areas

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