Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

Yukinari Sunatsuki; Masafumi Sakata; Susumu Matsuzaki; Naohide Matsumoto; Masaaki Kojima

doi:10.1246/cl.2001.1254

Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

Yukinari Sunatsuki, Masafumi Sakata, Susumu Matsuzaki, Naohide Matsumoto, Masaaki Kojima

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A novel spin crossover Fe(III) complex, [Fe(H₃L)](CIO₄),·(4-fim)·H₂O (H₃L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

Original language	English
Pages (from-to)	1254-1255
Number of pages	2
Journal	Chemistry Letters
Issue number	12
DOIs	https://doi.org/10.1246/cl.2001.1254
Publication status	Published - Jan 1 2001
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2001.1254

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title = "Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups",

abstract = "A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.",

author = "Yukinari Sunatsuki and Masafumi Sakata and Susumu Matsuzaki and Naohide Matsumoto and Masaaki Kojima",

year = "2001",

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journal = "Chemistry Letters",

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T1 - Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

AU - Sunatsuki, Yukinari

AU - Sakata, Masafumi

AU - Matsuzaki, Susumu

AU - Matsumoto, Naohide

AU - Kojima, Masaaki

PY - 2001/1/1

Y1 - 2001/1/1

N2 - A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

AB - A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

Abstract

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