Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)6](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

Tomoyuki Tajima; Takayo Sasaki; Takahiro Sasamori; Nobuhiro Takeda; Norihiro Tokitoh

doi:10.1039/b314010e

Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

Tomoyuki Tajima, Takayo Sasaki, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Thermal reactions of an overcrowded germacyclopropabenzene with hexacarbonyl complexes of group 6 metals resulted in the formation of the corresponding cyclic germoxycarbene complexes, i.e., 1,2-oxagermolan-5-ylidene pentacarbonyl metal complexes, via a novel mode of CO insertion reaction toward cyclopropabenzene derivatives.

Original language	English
Pages (from-to)	402-403
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/b314010e
Publication status	Published - Jan 1 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Tajima, T., Sasaki, T., Sasamori, T., Takeda, N., & Tokitoh, N. (2004). Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes. Chemical Communications, 4(4), 402-403. https://doi.org/10.1039/b314010e

Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes. / Tajima, Tomoyuki; Sasaki, Takayo; Sasamori, Takahiro et al.
In: Chemical Communications, Vol. 4, No. 4, 01.01.2004, p. 402-403.

Research output: Contribution to journal › Article › peer-review

Tajima, T, Sasaki, T, Sasamori, T, Takeda, N & Tokitoh, N 2004, 'Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)₆](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes', Chemical Communications, vol. 4, no. 4, pp. 402-403. https://doi.org/10.1039/b314010e

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