TMSCl-promoted electroreduction of triphenylphosphine oxide to triphenylphosphine

Hideo Tanaka; Tomotake Yano; Kazuma Kobayashi; Syogo Kamenoue; Manabu Kuroboshi; Hiromu Kawakubo

doi:10.1055/s-0030-1259529

TMSCl-promoted electroreduction of triphenylphosphine oxide to triphenylphosphine

Hideo Tanaka, Tomotake Yano, Kazuma Kobayashi, Syogo Kamenoue, Manabu Kuroboshi, Hiromu Kawakubo

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Direct reductive transformation of triphenylphosphine oxide to triphenylphosphine was performed successfully by electrolysis with TMSCl in an acetonitrile/BuBr/(Zn anode)-(Pt cathode)/undivided cell/constant current electrolysis system. A plausible ECEC mechanism involving the formation of silylated phosphorus radical is proposed.

Original language	English
Article number	U10210ST
Pages (from-to)	582-584
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-0030-1259529
Publication status	Published - Feb 10 2011

Keywords

electron transfer
phosphorus
reduction
silicon

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0030-1259529

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abstract = "Direct reductive transformation of triphenylphosphine oxide to triphenylphosphine was performed successfully by electrolysis with TMSCl in an acetonitrile/BuBr/(Zn anode)-(Pt cathode)/undivided cell/constant current electrolysis system. A plausible ECEC mechanism involving the formation of silylated phosphorus radical is proposed.",

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AU - Tanaka, Hideo

AU - Yano, Tomotake

AU - Kobayashi, Kazuma

AU - Kamenoue, Syogo

AU - Kuroboshi, Manabu

AU - Kawakubo, Hiromu

PY - 2011/2/10

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N2 - Direct reductive transformation of triphenylphosphine oxide to triphenylphosphine was performed successfully by electrolysis with TMSCl in an acetonitrile/BuBr/(Zn anode)-(Pt cathode)/undivided cell/constant current electrolysis system. A plausible ECEC mechanism involving the formation of silylated phosphorus radical is proposed.

AB - Direct reductive transformation of triphenylphosphine oxide to triphenylphosphine was performed successfully by electrolysis with TMSCl in an acetonitrile/BuBr/(Zn anode)-(Pt cathode)/undivided cell/constant current electrolysis system. A plausible ECEC mechanism involving the formation of silylated phosphorus radical is proposed.

KW - electron transfer

KW - phosphorus

KW - reduction

KW - silicon

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TMSCl-promoted electroreduction of triphenylphosphine oxide to triphenylphosphine

Abstract

Keywords

ASJC Scopus subject areas

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