Un Monophosphate Synth6tique de Sodium et de Cobalt: Na4Co7(PO4)6

Dilshat Kobashi; Shizuo Kohara; Junji Yamakawa; Akira Kawahara

doi:10.1107/S010827019701189X

Un Monophosphate Synth6tique de Sodium et de Cobalt: Na₄Co₇(PO₄)₆

Dilshat Kobashi, Shizuo Kohara, Junji Yamakawa, Akira Kawahara

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Tetrasodium heptacobalt hexaphosphate, a new monophosphate prepared by hydrothermal methods, comprises CoO₆ and CoO₄ coordination polyhedra connected to each other by corner and edge sharing to form zigzag layers parallel to the ab plane. These layers are interconnected by Co-O polyhedra and P-O tetrahedra via corner sharing to form a three-dimensional network. The Na⁺ ions are located in the tunnels running parallel to the a axis. This compound is isostructural with Na₄Ni₇(PO₄)₆.

Original language	French
Pages (from-to)	7-9
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1107/S010827019701189X
Publication status	Published - Jan 1 1998

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

Access to Document

10.1107/S010827019701189X

Cite this

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abstract = "Tetrasodium heptacobalt hexaphosphate, a new monophosphate prepared by hydrothermal methods, comprises CoO6 and CoO4 coordination polyhedra connected to each other by corner and edge sharing to form zigzag layers parallel to the ab plane. These layers are interconnected by Co-O polyhedra and P-O tetrahedra via corner sharing to form a three-dimensional network. The Na+ ions are located in the tunnels running parallel to the a axis. This compound is isostructural with Na4Ni7(PO4)6.",

author = "Dilshat Kobashi and Shizuo Kohara and Junji Yamakawa and Akira Kawahara",

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AU - Kawahara, Akira

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AB - Tetrasodium heptacobalt hexaphosphate, a new monophosphate prepared by hydrothermal methods, comprises CoO6 and CoO4 coordination polyhedra connected to each other by corner and edge sharing to form zigzag layers parallel to the ab plane. These layers are interconnected by Co-O polyhedra and P-O tetrahedra via corner sharing to form a three-dimensional network. The Na+ ions are located in the tunnels running parallel to the a axis. This compound is isostructural with Na4Ni7(PO4)6.

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