Unusual metal-dependent acceleration and deceleration in the metal-catalyzed hydrosilylation of olefin using pyridyldimethylsilanes

Kenichiro Itami; Koichi Mitsudo; Akira Nishino; Jun Ichi Yoshida

doi:10.1246/cl.2001.1088

Unusual metal-dependent acceleration and deceleration in the metal-catalyzed hydrosilylation of olefin using pyridyldimethylsilanes

Kenichiro Itami, Koichi Mitsudo, Akira Nishino, Jun Ichi Yoshida

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The Rh- and Pt-catalyzed hydrosilylations of olefin utilizing 2-pyridyl-, 3-pyridyl-, 4-pyridyl-, and phenyldimethylsilane are described. Whereas huge rate acceleration was observed with 2-PyMe₂SiH in the Rh-catalyzed reaction, huge rate deceleration was observed with 2-PyMe₂SiH and 4-PyMe₂SiH in the Pt-catalyzed reaction.

Original language	English
Pages (from-to)	1088-1089
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.2001.1088
Publication status	Published - Jan 1 2001
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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abstract = "The Rh- and Pt-catalyzed hydrosilylations of olefin utilizing 2-pyridyl-, 3-pyridyl-, 4-pyridyl-, and phenyldimethylsilane are described. Whereas huge rate acceleration was observed with 2-PyMe2SiH in the Rh-catalyzed reaction, huge rate deceleration was observed with 2-PyMe2SiH and 4-PyMe2SiH in the Pt-catalyzed reaction.",

author = "Kenichiro Itami and Koichi Mitsudo and Akira Nishino and Yoshida, {Jun Ichi}",

year = "2001",

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doi = "10.1246/cl.2001.1088",

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T1 - Unusual metal-dependent acceleration and deceleration in the metal-catalyzed hydrosilylation of olefin using pyridyldimethylsilanes

AU - Itami, Kenichiro

AU - Mitsudo, Koichi

AU - Nishino, Akira

AU - Yoshida, Jun Ichi

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The Rh- and Pt-catalyzed hydrosilylations of olefin utilizing 2-pyridyl-, 3-pyridyl-, 4-pyridyl-, and phenyldimethylsilane are described. Whereas huge rate acceleration was observed with 2-PyMe2SiH in the Rh-catalyzed reaction, huge rate deceleration was observed with 2-PyMe2SiH and 4-PyMe2SiH in the Pt-catalyzed reaction.

AB - The Rh- and Pt-catalyzed hydrosilylations of olefin utilizing 2-pyridyl-, 3-pyridyl-, 4-pyridyl-, and phenyldimethylsilane are described. Whereas huge rate acceleration was observed with 2-PyMe2SiH in the Rh-catalyzed reaction, huge rate deceleration was observed with 2-PyMe2SiH and 4-PyMe2SiH in the Pt-catalyzed reaction.

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U2 - 10.1246/cl.2001.1088

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

Unusual metal-dependent acceleration and deceleration in the metal-catalyzed hydrosilylation of olefin using pyridyldimethylsilanes

Abstract

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