Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I)

Tomoya Miura; Taisuke Sasaki; Tatsuro Harumashi; Masahiro Murakami

doi:10.1021/ja0575326

Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I)

Tomoya Miura, Taisuke Sasaki, Tatsuro Harumashi, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

New cyclization reactions forming vinylcyclopropanes were developed wherein an alkenylrhodium(I) possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent. By this protocol, a vinylcyclopropane was installed in a complex cyclic structure in a single operation via successive multiple carbon-carbon bond formations.

Original language	English
Pages (from-to)	2516-2517
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	8
DOIs	https://doi.org/10.1021/ja0575326
Publication status	Published - Mar 1 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0575326

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abstract = "New cyclization reactions forming vinylcyclopropanes were developed wherein an alkenylrhodium(I) possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent. By this protocol, a vinylcyclopropane was installed in a complex cyclic structure in a single operation via successive multiple carbon-carbon bond formations.",

author = "Tomoya Miura and Taisuke Sasaki and Tatsuro Harumashi and Masahiro Murakami",

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AU - Murakami, Masahiro

PY - 2006/3/1

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AB - New cyclization reactions forming vinylcyclopropanes were developed wherein an alkenylrhodium(I) possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent. By this protocol, a vinylcyclopropane was installed in a complex cyclic structure in a single operation via successive multiple carbon-carbon bond formations.

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Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I)

Abstract

ASJC Scopus subject areas

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