A geometrical isomeric pair of novel cobalt(III) complexes containing diphenylphosphine: Cis- and trans-[Co(dtc)2(PHPh2)2]BF4(dtc = N,N-dimethyldithiocarbamate)

Takayoshi Suzuki; Satoshi Iwatsuki; Hideo D. Takagi; Kazuo Kashiwabara

doi:10.1246/cl.2001.1068

A geometrical isomeric pair of novel cobalt(III) complexes containing diphenylphosphine: Cis- and trans-[Co(dtc)₂(PHPh₂)₂]BF₄(dtc = N,N-dimethyldithiocarbamate)

Takayoshi Suzuki, Satoshi Iwatsuki, Hideo D. Takagi, Kazuo Kashiwabara

研究成果 › 査読

4 被引用数 (Scopus)

抄録

The stable title cobalt(III) complexes containing PHPh₂ have been prepared and investigated for their crystal structures and spectroscopic properties. The cis-isomer was converted photochemically to the trans-isomer, which isomerized thermally to the original cis-isomer. The structural parameters and the ligand-field strengths of the PHPh₂ complexes were not predictable from the σ-donicity of PHPh₂.

本文言語	English
ページ（範囲）	1068-1069
ページ数	2
ジャーナル	Chemistry Letters
号	10
DOI	https://doi.org/10.1246/cl.2001.1068
出版ステータス	Published - 1月 1 2001
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2001.1068

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「A geometrical isomeric pair of novel cobalt(III) complexes containing diphenylphosphine: Cis- and trans-[Co(dtc)₂(PHPh₂)₂]BF₄(dtc = N,N-dimethyldithiocarbamate)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "The stable title cobalt(III) complexes containing PHPh2 have been prepared and investigated for their crystal structures and spectroscopic properties. The cis-isomer was converted photochemically to the trans-isomer, which isomerized thermally to the original cis-isomer. The structural parameters and the ligand-field strengths of the PHPh2 complexes were not predictable from the σ-donicity of PHPh2.",

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