@article{60aa15a926304a3a8f16c81f8345067a,
title = "A trinuclear chromium(iii) chlorocarbyne",
abstract = "Reduction of CCl4 by CrCl2 in THF afforded a trinuclear chromium(iii) carbyne [CrCl(thf)2]3(μ3-CCl)(μ-Cl)3. The chlorocarbyne complex reacted with aldehydes to afford chloroallylic alcohols and terminal alkynes. The mechanistic study proposed two competitive pathways via an α-chlorovinyl intermediate. ",
author = "Takashi Kurogi and Keiichi Irifune and Takahiro Enoki and Kazuhiko Takai",
note = "Funding Information: This work was financially supported by a Grant-in-Aid for Scientific Research (No. 18H03911) from MEXT, Japan. The DFT calculations were performed at the Research Center for Computational Science, Okazaki, Japan. The authors gratefully thank Prof. Hiroyuki Kawaguchi and Dr Yutaka Ishida at Tokyo Institute of Technology for elemental analyses of air-sensitive compounds. We also thank Ms Chihiro Isonaka at Okayama University for work on the preliminary study. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",
year = "2021",
month = may,
day = "25",
doi = "10.1039/d1cc01514a",
language = "English",
volume = "57",
pages = "5199--5202",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "42",
}