抄録
A tripodal hexadentate ligand containing three imidazole groups gives spin-crossover iron complexes in both the +II and the +III oxidation states. The tetrafluoroborate salt of the Fe(II) complex shows a gradual spin transition in the temperature range 110-270 K. The corresponding Fe(III) complex shows a spin transition above 150 K, and at 300 K ca. 87% of the Fe(III) ion is in the high-spin state.
本文言語 | English |
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ページ(範囲) | 350-351 |
ページ数 | 2 |
ジャーナル | Chemistry Letters |
巻 | 33 |
号 | 3 |
DOI | |
出版ステータス | Published - 3月 2004 |
ASJC Scopus subject areas
- 化学一般