A tripodal ligand containing three imidazole groups inducing spin crossover in both Fe(II) and Fe(III) complexes; structures and spin crossover behaviors of the complexes

Hiromi Ohta, Yukinari Sunatsuki, Masaaki Kojima, Seiichiro Iijima, Haruo Akashi, Naohide Matsumoto

研究成果査読

33 被引用数 (Scopus)

抄録

A tripodal hexadentate ligand containing three imidazole groups gives spin-crossover iron complexes in both the +II and the +III oxidation states. The tetrafluoroborate salt of the Fe(II) complex shows a gradual spin transition in the temperature range 110-270 K. The corresponding Fe(III) complex shows a spin transition above 150 K, and at 300 K ca. 87% of the Fe(III) ion is in the high-spin state.

本文言語English
ページ(範囲)350-351
ページ数2
ジャーナルChemistry Letters
33
3
DOI
出版ステータスPublished - 3月 2004

ASJC Scopus subject areas

  • 化学一般

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