A unique chelating effect of Sc(OTf)3 to organofluorine compounds

Hiroshi Kajiro; Atsunori Mori; Yasushi Nishihara; Tamejiro Hiyama

doi:10.1246/cl.1999.459

A unique chelating effect of Sc(OTf)₃ to organofluorine compounds

Hiroshi Kajiro, Atsunori Mori, Yasushi Nishihara, Tamejiro Hiyama

研究成果 › 査読

3 被引用数 (Scopus)

抄録

The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position β to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.

本文言語	English
ページ（範囲）	459-460
ページ数	2
ジャーナル	Chemistry Letters
号	6
DOI	https://doi.org/10.1246/cl.1999.459
出版ステータス	Published - 1月 1 1999
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.1999.459

他のファイルとリンク

引用スタイル

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