TY - JOUR
T1 - Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities
T2 - Synthesis of the first triphenylene derivatives having thiophene and metallafluorene moieties
AU - Saito, Masaichi
AU - Tanikawa, Tomoharu
AU - Tajima, Tomoyuki
AU - Guo, Jing Dong
AU - Nagase, Shigeru
PY - 2010/4/1
Y1 - 2010/4/1
N2 - Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities gave the first triphenylene derivatives whose two pairs of bay carbons are connected by two different heteroatom functionalities. Triphenyleno[1,12-bcd:4,5-b′c′d′]dithiophene, which had been only accessible through the very severe reaction conditions, was synthesized under the mild reaction conditions. Photophysical properties of newly-obtained heterolotriphenylene derivatives are discussed with theoretical calculations.
AB - Arching a bay area of triphenyleno[1,12-bcd]thiophene with group 14 functionalities gave the first triphenylene derivatives whose two pairs of bay carbons are connected by two different heteroatom functionalities. Triphenyleno[1,12-bcd:4,5-b′c′d′]dithiophene, which had been only accessible through the very severe reaction conditions, was synthesized under the mild reaction conditions. Photophysical properties of newly-obtained heterolotriphenylene derivatives are discussed with theoretical calculations.
KW - Electronic absorption
KW - Fluorescence
KW - Silolotriphenyleno[1,12-bcd]thiophene
KW - Stannolotriphenyleno[1,12-bcd]thiophene
KW - Triphenyleno[1,12-bcd:4,5-b′c′d′]dithiophene
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U2 - 10.1016/j.jorganchem.2009.11.039
DO - 10.1016/j.jorganchem.2009.11.039
M3 - Article
AN - SCOPUS:77749330139
SN - 0022-328X
VL - 695
SP - 1035
EP - 1041
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 7
ER -