Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki; Hideo D. Takagi; Kazuo Kashiwabara

doi:10.1107/S0108270101018406

Bis(μ-N, N-dimethyldithiocarbamato-κ³ S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ²S, S′)cobalt(III)] bis(hexafluorophosphate)

Takayoshi Suzuki, Hideo D. Takagi, Kazuo Kashiwabara

研究成果 › 査読

1 被引用数 (Scopus)

抄録

Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co₂(C₃H₆NS₂)₄] (C₈H₁₁O₂P)₂](PF₆) ₂ were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C₂ symmetry and a dinuclear structure.

本文言語	English
ページ（範囲）	m95-m97
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	58
号	2
DOI	https://doi.org/10.1107/S0108270101018406
出版ステータス	Published - 2月 2002
外部発表	はい

ASJC Scopus subject areas

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270101018406

他のファイルとリンク

フィンガープリント

「Bis(μ-N, N-dimethyldithiocarbamato-κ³ S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ²S, S′)cobalt(III)] bis(hexafluorophosphate)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)",

abstract = "Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.",

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T1 - Bis(μ-N, N-dimethyldithiocarbamato-κ3 S, S′:S′)bis[(dimethoxyphenyl-phosphane-κP) (N, N-dimethyldithiocarbamato-κ2S, S′)cobalt(III)] bis(hexafluorophosphate)

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AU - Kashiwabara, Kazuo

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N2 - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

AB - Several series of cobalt (III) complexes containing monodentate P-donor ligands were synthesized and their structures were compared. Purple prismatic crystals of [Co2(C3H6NS2)4] (C8H11O2P)2](PF6) 2 were obtained by repeated recrystallization. One of the ligands was dissociated form the cobalt (III) center and the resulting complex fragment experienced dimerization. The complex cation was found to have a crystallographically imposed C2 symmetry and a dinuclear structure.

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