Chiral Acyclic Nitrone Bearing Protected Vicinal Diol Controller Providing Single π(C=N)-Face in [3+2] Cycloaddition Reactions

Seiki Saito, Teruhiko Ishikawa, Norihisa Kishimoto, Tomonari Kohara, Toshio Moriwake

研究成果査読

17 被引用数 (Scopus)

抄録

Acyclic chiral (Z)-nitrone (4) bearing the protected vicinal diol controller has been developed with the intention of shielding one of its π-(C=N) diastereofaces. The intermolecular [3+2] cycloaddition reactions of 4 with various olefins resulted in perfect discrimination of the nitrone faces though that of the olefins depended on their structures.

本文言語English
ページ(範囲)282-284
ページ数3
ジャーナルSynlett
1994
4
DOI
出版ステータスPublished - 4月 1 1994

ASJC Scopus subject areas

  • 有機化学

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