Chiral Bifunctional Metalloporphyrin Catalysts for Kinetic Resolution of Epoxides with Carbon Dioxide

Chihiro Maeda, Mayato Mitsuzane, Tadashi Ema

研究成果査読

26 被引用数 (Scopus)

抄録

Chiral binaphthyl-strapped Zn(II) porphyrins with triazolium halide units were synthesized as bifunctional catalysts for kinetic resolution of epoxides with CO 2 . Several catalysts were screened by changing the linker length and nucleophilic counteranions, and the optimized catalyst accelerated the enantioselective reaction at ambient temperature to produce optically active cyclic carbonates and epoxides.

本文言語English
ページ(範囲)1853-1856
ページ数4
ジャーナルOrganic Letters
21
6
DOI
出版ステータスPublished - 3月 15 2019

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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