Conversion of rectangular tetrasulfide ligand in tetrarhodium complex, [{(RhCp*)2(μ-CH2)2} 24-S4)]2+ (Cp* = η5-C5Me5), into disulfide ligands in dirhodium complex, [(RhCp*)2(μ-CH2)2(μ-S2)] by chemical reduction

Takanori Nishioka, Shigeyuki Nakamura, Yuichi Kaneko, Takayoshi Suzuki, Isamu Kinoshita, Syun Ichi Kiyooka, Kiyoshi Isobe

研究成果査読

17 被引用数 (Scopus)

抄録

Reaction of [{(RhCp*)2(μ-CH2)2} 24-S4)]2+ (Cp*=η5-C5Me5) (1) containing a rectangular S4 ligand with the reducing agent of NaBH4 affords [(RhCp*)2(μ-CH2)2(μ-S2)] (2) confirmed by FAB mass and 1H NMR spectra. This disulfide complex is so air-sensitive that the S2 ligand is easily oxygenated by oxygen to give an SSO ligand in [(RhCp*)2(μ-CH2)2(μ-SSO)] (3) whose structure is determined by X-ray analysis.

本文言語English
ページ(範囲)911-912
ページ数2
ジャーナルChemistry Letters
10
DOI
出版ステータスPublished - 1996
外部発表はい

ASJC Scopus subject areas

  • 化学一般

フィンガープリント

「Conversion of rectangular tetrasulfide ligand in tetrarhodium complex, [{(RhCp*)2(μ-CH2)2} 24-S4)]2+ (Cp* = η5-C5Me5), into disulfide ligands in dirhodium complex, [(RhCp*)2(μ-CH2)2(μ-S2)] by chemical reduction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル