Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

Michihiro Miyake; Osamu Kaji; Shin Nagahara; Takashi Suzuki

doi:10.1039/F29868200687

Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

Michihiro Miyake
, Osamu Kaji
, Shin Nagahara
, Takashi Suzuki

研究成果 › 査読

1 被引用数 (Scopus)

抄録

The coordination structure of Zn^II ions in HCONH₂-HCOONH₄-ZnO solution, where the molar ratio of HCOONH₄ and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that Zn^II ions from mononuclear Zn(HCOO)₂(HCONH₂)₂ tetrahedra with a Zn-O bond length of 1.99 Å in HCONH₂-HCOONH₄ solution.

本文言語	English
ページ（範囲）	687-694
ページ数	8
ジャーナル	Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
巻	82
号	4
DOI	https://doi.org/10.1039/F29868200687
出版ステータス	Published - 1986
外部発表	はい

ASJC Scopus subject areas

原子分子物理学および光学
物理化学および理論化学

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10.1039/F29868200687

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引用スタイル

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abstract = "The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 {\AA} in HCONH2-HCOONH4 solution.",

author = "Michihiro Miyake and Osamu Kaji and Shin Nagahara and Takashi Suzuki",

year = "1986",

doi = "10.1039/F29868200687",

language = "English",

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pages = "687--694",

journal = "Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics",

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AU - Miyake, Michihiro

AU - Kaji, Osamu

AU - Nagahara, Shin

AU - Suzuki, Takashi

PY - 1986

Y1 - 1986

N2 - The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 Å in HCONH2-HCOONH4 solution.

AB - The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 Å in HCONH2-HCOONH4 solution.

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