Electric Potential Distribution on Lithium Ion Battery Cathodes Measured Using Terahertz Chemical Microscopy

Toshihiko Kiwa, Yuki Akiwa, Hayato Fujita, Takashi Teranishi, Kenji Sakai, Hidetoshi Nose, Masaki Kobayashi, Keiji Tsukada

研究成果査読

10 被引用数 (Scopus)

抄録

A terahertz chemical microscope has been developed to visualize electric potential distribution on lithium ion battery cathodes during battery operation. A sensing plate comprising a Si film grown epitaxially on a sapphire substrate was used as a terahertz emitter. The amplitude of terahertz radiation from the sensing plate could be related to the electric potential at the exact point where a femtosecond laser illuminated. Here, the sensing plate was integrated into a conventional can-type lithium ion battery and terahertz radiation from the sensing plate was observed during battery operation between 2.7 and 4.2 V. By scanning the laser, the distribution of terahertz amplitude radiated from the sensing plate was observed, which could be related to the electric potential distribution on the electrodes of the batteries. Localized electric potential could be visualized as the amplitude of terahertz radiation generated in the sensing plate, which was integrated beneath the battery electrode.
本文言語English
ページ(範囲)430-437
ジャーナルJournal of Infrared, Millimeter, and Terahertz Waves
41
4
DOI
出版ステータスPublished - 11月 1 2019
外部発表はい

ASJC Scopus subject areas

  • 放射線
  • 器械工学
  • 凝縮系物理学
  • 電子工学および電気工学

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