Electronic structure of K-doped C60 monolayer films adsorbed on Si(0 0 1)-(2 × 1) and Si(1 1 1)-(7 × 7) surfaces

Kazuyuki Sakamoto, Takanori Wakita, Daiyu Kondo, Ayumi Harasawa, Toyohiko Kinoshita, Wakio Uchida, Atsuo Kasuya

研究成果査読

5 被引用数 (Scopus)

抄録

We have measured the valence spectra of K-doped C60 monolayer films adsorbed on Si(0 0 1)-(2 × 1) and Si(1 1 1)-(7 × 7) surfaces. No density of states is observed at the Fermi level for the undoped C60 monolayer films on both Si surfaces. After a small K doping, a density of states is clearly observed at the Fermi level on a Si(0 0 1)-(2 × 1) surface. On the other hand, no density of states is observed at the Fermi level at any amount of K doping on a Si(1 1 1)-(7 × 7) surface. The difference observed on both Si surfaces indicates that the symmetry of C60 molecules is almost the same as that in solid phase on a Si(0 0 1)-(2 × 1) surface, and is broken due to a stronger C60-substrate and/or C60-C60 interaction on the Si(1 1 1)-(7 × 7) one.

本文言語English
ページ(範囲)63-72
ページ数10
ジャーナルSurface Science
499
1
DOI
出版ステータスPublished - 2月 20 2002
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学
  • 表面および界面
  • 表面、皮膜および薄膜
  • 材料化学

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