Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(II) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand

Ryoji Mitsuhashi; Kasper S. Pedersen; Takaaki Ueda; Takayoshi Suzuki; Jesper Bendix; Masahiro Mikuriya

doi:10.1039/c8cc04756a

Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(II) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand

Ryoji Mitsuhashi, Kasper S. Pedersen, Takaaki Ueda, Takayoshi Suzuki, Jesper Bendix, Masahiro Mikuriya

異分野基礎科学研究所

研究成果 › 査読

30 被引用数 (Scopus)

抄録

A new cobalt(ii) complex bearing a pair of cobalt(iii) tris-chelate complexes as metalloligands was prepared. The Co^II ion possesses an ideal trigonal antiprismatic geometry because of the intermolecular hydrogen-bonds between the metalloligands via counter anions. This complex exhibits slow magnetic relaxation under a dc field reminiscent of a single-molecule magnet behavior.

本文言語	English
ページ（範囲）	8869-8872
ページ数	4
ジャーナル	Chemical Communications
巻	54
号	64
DOI	https://doi.org/10.1039/c8cc04756a
出版ステータス	Published - 2018

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/c8cc04756a

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引用スタイル

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AU - Mikuriya, Masahiro

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