Grafting chelating groups on 2D carbon for selective heavy metal adsorption

Risa Shibahara, Kazuhide Kamiya, Yuta Nishina

研究成果査読

4 被引用数 (Scopus)

抄録

Iminodiacetic acid (IDA) is a tridentate ligand, which can capture metal ions by forming two fused five-membered chelate rings. In this study, we fixed IDA moieties onto a two-dimensional nanocarbon, graphene oxide (GO), to obtain materials with high and selective adsorption of metal ions. The synthesis conditions for the GO-IDA composites were optimized, then their structures were characterized by infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and CHN elemental analysis. In addition, the heavy-metal removal efficiency and selectivity of the GO-IDA composites with different length alkyl linkers between the GO and IDA were investigated. An aqueous solution containing 10 metal ions (Al, As, B, Cd, Cr, Cu, Mn, Pb, Se, and Zn) was used as a model for contaminated water at pH 7, and the interactions of the ions with GO-IDA were in the order of Cu > Pb > As > B > Zn > Al ≈ Se. The interaction between Cu and GO-IDA was confirmed by XPS and extended X-ray absorption fine structure (EXAFS), which showed that Cu was coordinated to IDA.

本文言語English
ページ(範囲)5823-5829
ページ数7
ジャーナルNanoscale Advances
3
20
DOI
出版ステータスPublished - 10月 21 2021

ASJC Scopus subject areas

  • 化学一般
  • 工学一般
  • バイオエンジニアリング
  • 原子分子物理学および光学
  • 材料科学一般

フィンガープリント

「Grafting chelating groups on 2D carbon for selective heavy metal adsorption」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル