Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai; Yoshito Ikawa

doi:10.1021/ol025784v

Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides

Kazuhiko Takai, Yoshito Ikawa

研究成果 › 査読

63 被引用数 (Scopus)

抄録

Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

本文言語	English
ページ（範囲）	1727-1729
ページ数	3
ジャーナル	Organic Letters
巻	4
号	10
DOI	https://doi.org/10.1021/ol025784v
出版ステータス	Published - 5月 16 2002
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol025784v

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引用スタイル

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Y1 - 2002/5/16

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AB - Matrix presented Fast transmetalation of an allyl group from indium to gallium enables the assembly of a catalytic cycle of indium, which accelerates the formation of allylgallium sesquibromide. A solution of allylaluminum sesquibromide in THF is also prepared from allyl bromide and aluminum metal under indium catalysis.

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