Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

Y. Takaguchi; H. Fujihara; N. Furukawa

doi:10.1016/0022-328X(95)05491-7

Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

Y. Takaguchi
, H. Fujihara
, N. Furukawa

研究成果 › 査読

16 被引用数 (Scopus)

抄録

Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO₂] were prepared and variable-temperature ¹H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.

本文言語	English
ページ（範囲）	49-52
ページ数	4
ジャーナル	Journal of Organometallic Chemistry
巻	498
号	1
DOI	https://doi.org/10.1016/0022-328X(95)05491-7
出版ステータス	Published - 8月 9 1995
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学
無機化学
材料化学

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10.1016/0022-328X(95)05491-7

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title = "Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes",

abstract = "Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO2] were prepared and variable-temperature 1H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.",

keywords = "Chalcogen, Dynamics, Group 16, Hindered ligands, Nuclear magnetic resonances, Tellurium",

author = "Y. Takaguchi and H. Fujihara and N. Furukawa",

note = "Funding Information: This work was supportedb y the Ministry of Education, Sciencea nd Culture,J apan (Priority area: Grant No. 05236205).",

year = "1995",

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T1 - Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

AU - Takaguchi, Y.

AU - Fujihara, H.

AU - Furukawa, N.

N1 - Funding Information: This work was supportedb y the Ministry of Education, Sciencea nd Culture,J apan (Priority area: Grant No. 05236205).

PY - 1995/8/9

Y1 - 1995/8/9

N2 - Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO2] were prepared and variable-temperature 1H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.

AB - Dihalo- and diacyloxydi(2,6-dimethylphenyl)telluranes [10-Te-C2X2; X = halogen and RCO2] were prepared and variable-temperature 1H NMR studies revealed that these telluranes were composed of the sterically congested rotamers. The first examples of the activation parameters for rotation of the TeC bonds were obtained in D NMR experiments.

KW - Chalcogen

KW - Dynamics

KW - Group 16

KW - Hindered ligands

KW - Nuclear magnetic resonances

KW - Tellurium

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UR - https://www.scopus.com/pages/publications/0002190623#tab=citedBy

U2 - 10.1016/0022-328X(95)05491-7

DO - 10.1016/0022-328X(95)05491-7

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AN - SCOPUS:0002190623

SN - 0022-328X

VL - 498

SP - 49

EP - 52

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Molecular dynamics of sterically hindered dihalo- and diacyloxydiaryltelluranes

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