Novel synthesis of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtius rearrangement

Daisuke Sawada, Shinya Sasayama, Hideyo Takahashi, Shiro Ikegami

研究成果査読

17 被引用数 (Scopus)

抄録

We describe a novel synthesis of various carbamate- and urea-linked disaccharides stereospecifically using sugar carboxylic acids and sugar alcohols or sugar amines by the modified Curtius rearrangement. In this reaction, the reactivity of each hydroxyl group in glucose as an acceptor has been disclosed. Furthermore, we applied this method to the synthesis of carbamate-linked oligosaccharides including a dendritic molecule.

本文言語English
ページ(範囲)8780-8788
ページ数9
ジャーナルTetrahedron
64
37
DOI
出版ステータスPublished - 9月 8 2008
外部発表はい

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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