New Schiff-base compound (E)-2-(2,5-dimethoxybenzylideneamino)phenol (1) was synthesized and characterized by elemental analyses, FT-IR and 1H-NMR spectroscopy and single crystal X-ray diffraction. Molecular orbital calculation has been carried out for 1 by using HF method at 6-31G basis set. The title compound 1 crystallizes in monoclinic system, space group C2/c, with a = 19.4581(13) Å, b = 9.5805(5) Å, β = 93.471(2)°, V = 2575.9(3) Å3 and Z = 8. In the crystal structure two molecules are stabilized by a pair of intermolecular O1- H1•••N1i hydrogen bonds. The dimeric units are further linked via C6-H6•••O3ii hydrogen bond.
ASJC Scopus subject areas
- 化学 (全般)