Organophotoredox-catalyzed intermolecular Oxa-[4+2] cycloaddition reactions

Kenta Tanaka, Daichi Omata, Yosuke Asada, Yujiro Hoshino, Kiyoshi Honda

研究成果査読

21 被引用数 (Scopus)

抄録

An intermolecular oxa-[4+2] cycloaddition reaction promoted by a thioxanthylium photoredox catalyst under irradiation with green light has been developed. The reaction of ortho-quinone methides with styrenes smoothly affords the desired cycloadducts. Especially styrenes bearing electron-donating groups are efficiently transformed in this reaction. This method represents a sustainable way to carry out oxa-[4+2] cycloaddition reactions using only a catalytic amount of a photocatalyst and visible light.

本文言語English
ページ(範囲)10669-10678
ページ数10
ジャーナルJournal of Organic Chemistry
84
17
DOI
出版ステータスPublished - 9月 6 2019
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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