Palladium- and base-free synthesis of conjugated ynones by cross-coupling reactions of alkynylboronates with acid chlorides mediated by CuCl

Yasushi Nishihara, Daisuke Saito, Eiji Inoue, Yoshiaki Okada, Mikihiro Miyazaki, Yoshiaki Inoue, Kentaro Takagi

研究成果査読

29 被引用数 (Scopus)

抄録

Alkynylboronates can be employed as a practical and versatile precursor for a variety of π-conjugated organic compounds. In the presence of Cu(I) salt, cross-coupling reactions of acid chlorides with alkynylboronates giving rise to the corresponding conjugated ynones takes place readily in aprotic polar solvents such as DMI under neutral conditions.

本文言語English
ページ(範囲)306-308
ページ数3
ジャーナルTetrahedron Letters
51
2
DOI
出版ステータスPublished - 1月 13 2010

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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