抄録
(Matrix presented) Modified aluminum catalyst 2 was found to be highly effective for Oppenauer (OPP) oxidation of alcohols under mild conditions. For example, oxidation of carveol in toluene with t-BuCHO (1.2 equiv) as a hydride acceptor in the presence of 2 (1 mol %) proceeded smoothly at 21°C to give carvone in 94% yield after 1 h. A practical aspect of this system was highlighted by the facile OPP oxidation of terpenoids and steroids with 1.2-3.0 equiv of acetone and 2 (3-5 mol %).
| 本文言語 | English |
|---|---|
| ページ（範囲） | 2669-2672 |
| ページ数 | 4 |
| ジャーナル | Organic Letters |
| 巻 | 4 |
| 号 | 16 |
| DOI | |
| 出版ステータス | Published - 8月 8 2002 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学