Stereoselective addition of α-chloro allylic chromium reagents to aldehydes

Kazuhiko Takai; Yasutaka Kataoka; Kiitiro Utimoto

doi:10.1016/S0040-4039(00)99368-7

Stereoselective addition of α-chloro allylic chromium reagents to aldehydes

Kazuhiko Takai, Yasutaka Kataoka, Kiitiro Utimoto

研究成果 › 査読

16 被引用数 (Scopus)

抄録

Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl₂ in THF-DMF at 25°C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96% yield under high stereocontrol.

本文言語	English
ページ（範囲）	4389-4392
ページ数	4
ジャーナル	Tetrahedron Letters
巻	30
号	33
DOI	https://doi.org/10.1016/S0040-4039(00)99368-7
出版ステータス	Published - 1989
外部発表	はい

ASJC Scopus subject areas

生化学
創薬
有機化学

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10.1016/S0040-4039(00)99368-7

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title = "Stereoselective addition of α-chloro allylic chromium reagents to aldehydes",

abstract = "Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25°C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96% yield under high stereocontrol.",

author = "Kazuhiko Takai and Yasutaka Kataoka and Kiitiro Utimoto",

year = "1989",

doi = "10.1016/S0040-4039(00)99368-7",

language = "English",

volume = "30",

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journal = "Tetrahedron Letters",

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T1 - Stereoselective addition of α-chloro allylic chromium reagents to aldehydes

AU - Takai, Kazuhiko

AU - Kataoka, Yasutaka

AU - Utimoto, Kiitiro

PY - 1989

Y1 - 1989

N2 - Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25°C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96% yield under high stereocontrol.

AB - Treatment of a solution of 1,1-dichloro-2-butene and benzaldehyde with CrCl2 in THF-DMF at 25°C for 1 h gave threo-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol in 96% yield under high stereocontrol.

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U2 - 10.1016/S0040-4039(00)99368-7

DO - 10.1016/S0040-4039(00)99368-7

M3 - Article

AN - SCOPUS:0001646542

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

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ER -

Stereoselective addition of α-chloro allylic chromium reagents to aldehydes

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