Stereoselective synthesis and absolute configuration of the C1′-C25′ fragment of symbiodinolide

Hiroyoshi Takamura, Takeshi Murata, Takahiro Asai, Isao Kadota, Daisuke Uemura

研究成果査読

20 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Stereoselective synthesis of the C1′-C25′ fragment of symbiodinolide, which was obtained as a degraded product from symbiodinolide by alkaline hydrolysis, has been accomplished. The synthetic route features Kotsuki coupling and Julia-Kocienski olefination in the introduction of the side chains. This enantioand stereoselective synthesis has established the absolute configuration of the C1′-C25′ fragment.

本文言語English
ページ(範囲)6658-6666
ページ数9
ジャーナルJournal of Organic Chemistry
74
17
DOI
出版ステータスPublished - 9月 4 2009

ASJC Scopus subject areas

  • 有機化学

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