¹¹³Cd MAS NMR study of cadmium halides and their salts

¹¹³Cd magic-angle spinning (MAS) NMR spectra have been measured of twenty-three kinds of Cd²⁺-containing halide crystals with known structures to determine the isotropic chemical shifts δ_iso. The δ_iso values of halogen coordination polyhedra largely changed with the kind and the coordination number of halogen. The relationship between the δ_iso values and the halogen coordination environments around Cd²⁺ was revealed.