Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)2]BF4 and dimeric [Cu2(2,3,2-SPPS)2](BF4)2

Kyoko Noda, Tetsuya Sasaki, Satoshi Iwatsuki, Kazuo Kashiwabara, Takayoshi Suzuki, Hideo D. Takagi

研究成果査読

5 被引用数 (Scopus)

抄録

Mononuclear and binuclear complexes of Cu(I) with bidentate and quadridentate phosphine-thioether hybrid ligands were successfully isolated for the first time by mixing aqueous copper(II) with each corresponding ligand: the structures of these complexes were analyzed by the X-ray crystallographic method and the synthetic route for these complexes was clarified on the basis of the electrochemical behaviors of these complexes in solution.

本文言語English
ページ(範囲)526-532
ページ数7
ジャーナルInorganica Chimica Acta
357
2
DOI
出版ステータスPublished - 1月 30 2004
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

フィンガープリント

「Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)2]BF4 and dimeric [Cu2(2,3,2-SPPS)2](BF4)2」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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