Synthesis of 2-Substituted Propenes by Bidentate Phosphine-Assisted Methylenation of Acyl Fluorides and Acyl Chlorides with AlMe 3

Xiu Wang, Zhenhua Wang, Yuya Asanuma, Yasushi Nishihara

研究成果査読

14 被引用数 (Scopus)

抄録

Bidentate phosphine-assisted methylenation of acyl fluorides and acyl chlorides with substituted with aryl, alkenyl, and alkyl groups trimethylaluminum afforded an array of 2-substituted propene derivatives. The addition of a catalytic amount of DPPM increased an efficiency of the reactions. Trimethylaluminum as the methylenation reagent not only eliminates the presynthesis of methylene transfer reagent, but provides an efficient method for the synthesis of a series of 2-substituted propenes.

本文言語English
ページ(範囲)3640-3643
ページ数4
ジャーナルOrganic Letters
21
10
DOI
出版ステータスPublished - 5月 17 2019

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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