Synthesis of cyclic 1-alkenylboronates via Zr-mediated double functionalization of alkynylboronates and sequential Ru-catalyzed ring-closing olefin metathesis

Yasushi Nishihara; Masato Suetsugu; Daisuke Saito; Megumi Kinoshita; Masayuki Iwasaki

doi:10.1021/ol400896u

Synthesis of cyclic 1-alkenylboronates via Zr-mediated double functionalization of alkynylboronates and sequential Ru-catalyzed ring-closing olefin metathesis

Yasushi Nishihara, Masato Suetsugu, Daisuke Saito, Megumi Kinoshita, Masayuki Iwasaki

異分野基礎科学研究所

研究成果 › 査読

15 被引用数 (Scopus)

抄録

Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.

本文言語	English
ページ（範囲）	2418-2421
ページ数	4
ジャーナル	Organic Letters
巻	15
号	10
DOI	https://doi.org/10.1021/ol400896u
出版ステータス	Published - 5月 17 2013

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol400896u

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引用スタイル

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abstract = "Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.",

author = "Yasushi Nishihara and Masato Suetsugu and Daisuke Saito and Megumi Kinoshita and Masayuki Iwasaki",

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T1 - Synthesis of cyclic 1-alkenylboronates via Zr-mediated double functionalization of alkynylboronates and sequential Ru-catalyzed ring-closing olefin metathesis

AU - Nishihara, Yasushi

AU - Suetsugu, Masato

AU - Saito, Daisuke

AU - Kinoshita, Megumi

AU - Iwasaki, Masayuki

PY - 2013/5/17

Y1 - 2013/5/17

N2 - Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.

AB - Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.

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