Synthesis of dendrimer-type viologen and its use in Pd-mediated homocoupling of aryl halides

Manabu Kuroboshi; Atsuki Kojima; Hideo Tanaka

doi:10.3987/COM-17-13812

Synthesis of dendrimer-type viologen and its use in Pd-mediated homocoupling of aryl halides

Manabu Kuroboshi, Atsuki Kojima, Hideo Tanaka

研究成果 › 査読

1 被引用数 (Scopus)

抄録

Dendrimer-type viologen (V²⁺.D.) was prepared from mesitylene and 4.4′-bipyridyl. Electroreduction of V²⁺.D. gave the corresponding quinoid (V⁰.D.), which promoted Pd-catalyzed homocoupling of aryl bromides Ar-Br to give the corresponding biaryls Ar-Ar in moderate to good yields.

本文言語	English
ページ（範囲）	2132-2140
ページ数	9
ジャーナル	Heterocycles
巻	94
号	11
DOI	https://doi.org/10.3987/COM-17-13812
出版ステータス	Published - 2017

ASJC Scopus subject areas

分析化学
薬理学
有機化学

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10.3987/COM-17-13812

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title = "Synthesis of dendrimer-type viologen and its use in Pd-mediated homocoupling of aryl halides",

abstract = "Dendrimer-type viologen (V2+.D.) was prepared from mesitylene and 4.4′-bipyridyl. Electroreduction of V2+.D. gave the corresponding quinoid (V0.D.), which promoted Pd-catalyzed homocoupling of aryl bromides Ar-Br to give the corresponding biaryls Ar-Ar in moderate to good yields.",

author = "Manabu Kuroboshi and Atsuki Kojima and Hideo Tanaka",

note = "Publisher Copyright: {\textcopyright} 2017 The Japan Institute of Heterocyclic Chemistry.",

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AU - Kuroboshi, Manabu

AU - Kojima, Atsuki

AU - Tanaka, Hideo

PY - 2017

Y1 - 2017

N2 - Dendrimer-type viologen (V2+.D.) was prepared from mesitylene and 4.4′-bipyridyl. Electroreduction of V2+.D. gave the corresponding quinoid (V0.D.), which promoted Pd-catalyzed homocoupling of aryl bromides Ar-Br to give the corresponding biaryls Ar-Ar in moderate to good yields.

AB - Dendrimer-type viologen (V2+.D.) was prepared from mesitylene and 4.4′-bipyridyl. Electroreduction of V2+.D. gave the corresponding quinoid (V0.D.), which promoted Pd-catalyzed homocoupling of aryl bromides Ar-Br to give the corresponding biaryls Ar-Ar in moderate to good yields.

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DO - 10.3987/COM-17-13812

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Synthesis of dendrimer-type viologen and its use in Pd-mediated homocoupling of aryl halides

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