Synthesis of microporous polymers with exposed C60 surfaces by polyesterification of fullerenol

Hirotomo Nishihara; Akio Harigaya; Alberto Castro-Muñiz; Mao Ohwada; Takashi Kyotani; Yuta Nishina

doi:10.1039/d2cc00728b

Synthesis of microporous polymers with exposed C₆₀ surfaces by polyesterification of fullerenol

Hirotomo Nishihara, Akio Harigaya, Alberto Castro-Muñiz, Mao Ohwada, Takashi Kyotani, Yuta Nishina

異分野融合先端研究コア

研究成果 › 査読

抄録

Microporous polymers with exposed C₆₀ surfaces have been synthesized by a new pathway of crosslinking fullerenol and terephthaloyl chloride or 1,3,5-benzenetricarbonyl trichloride via esterification. The resulting polymers are insoluble solids containing a large ratio of C₆₀ with hydroxy groups and possess micropores with high specific surface area up to 657 m² g⁻¹. The microporous polymers thus obtained exhibit enhanced hydrogen spillover, which is a unique property of the C₆₀ surface.

本文言語	English
ジャーナル	Chemical Communications
DOI	https://doi.org/10.1039/d2cc00728b
出版ステータス	Accepted/In press - 2022

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

文献へのアクセス

10.1039/d2cc00728b

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引用スタイル

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AU - Kyotani, Takashi

AU - Nishina, Yuta

PY - 2022

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