Synthesis of prenylarenes and related (multisubstituted allyl)arenes from aryl halides and homoallyl alcohols via palladium-catalyzed retro-allylation

Masayukt Iwasaki; Hideki Yorimttsu; Koiehiro Oshima

doi:10.1246/bcsj.82.249

Synthesis of prenylarenes and related (multisubstituted allyl)arenes from aryl halides and homoallyl alcohols via palladium-catalyzed retro-allylation

Masayukt Iwasaki
, Hideki Yorimttsu
, Koiehiro Oshima

研究成果 › 査読

18 被引用数 (Scopus)

抄録

The reactions of aryl halides with 2,3,3-trimethyl-4-penten-2-ol in the presence of a palladium catalyst result in prenyl transfer from the alcohol to aryl halides via retro-allylation, yielding prenylarenes. Other multisubstituted allyl groups such as the 2,3-dίmethyl-2-butenyl group are introduced to aromatic rings.

本文言語	English
ページ（範囲）	249-253
ページ数	5
ジャーナル	Bulletin of the Chemical Society of Japan
巻	82
号	2
DOI	https://doi.org/10.1246/bcsj.82.249
出版ステータス	Published - 2009
外部発表	はい

ASJC Scopus subject areas

化学一般

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10.1246/bcsj.82.249

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引用スタイル

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