The Diels-Alder reaction using a vinyl sulfoxide activated by the participation of a neighboring epoxide group

Hitoshi Abe, Daisuke Tsuchida, Setsuo Kashino, Yasuo Takeuchi, Takashi Harayama

研究成果査読

6 被引用数 (Scopus)

抄録

A vinyl sulfoxide, which is considered to be a moderately reactive dienophile, could be activated by neighboring participation of an epoxide group. The Diels-Alder reaction of ortho-epoxyphenyl vinyl sulfoxide with cyclopentadiene in the presence of Yb(OTf)3 proceeded smoothly even at room temperature to afford the epoxy-opened cycloadducts with moderate stereoselectivity.

本文言語English
ページ(範囲)833-837
ページ数5
ジャーナルChemical and Pharmaceutical Bulletin
47
6
DOI
出版ステータスPublished - 6月 1999

ASJC Scopus subject areas

  • 化学 (全般)
  • 創薬

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