Thyminate(2-)-bridged cyclic tetranuclear rhodium(III) complexes formed by a template of a sodium, calcium or lanthanoid ion

Ayana Kashima; Mika Sakate; Hiromi Ota; Akira Fuyuhiro; Yukinari Sunatsuki; Takayoshi Suzuki

doi:10.1039/c4cc09087j

Thyminate(2-)-bridged cyclic tetranuclear rhodium(III) complexes formed by a template of a sodium, calcium or lanthanoid ion

Ayana Kashima, Mika Sakate, Hiromi Ota, Akira Fuyuhiro, Yukinari Sunatsuki, Takayoshi Suzuki

研究成果 › 査読

15 被引用数 (Scopus)

抄録

In the thyminate(2-)-bridged tetranuclear Cp∗Rh^III complexes incorporating a Na⁺, Ca²⁺ or Ln³⁺ cation, homochiral aggregation of four Rh^III centres was achieved to form metallacalix[4]arene-type clusters. The thyminate(2-) bridged two Rh^III and the third metal ion with a μ₃-1κN¹:2κ²N³,O²:3κO² mode in the Na⁺ and Ca²⁺ complexes, while in the Ln³⁺ analogues it exhibited a different bridging mode, μ₃-1κN¹:2κ²N³,O⁴:3κO².

本文言語	English
ページ（範囲）	1889-1892
ページ数	4
ジャーナル	Chemical Communications
巻	51
号	10
DOI	https://doi.org/10.1039/c4cc09087j
出版ステータス	Published - 2月 4 2015

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/c4cc09087j

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引用スタイル

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abstract = "In the thyminate(2-)-bridged tetranuclear Cp∗RhIII complexes incorporating a Na+, Ca2+ or Ln3+ cation, homochiral aggregation of four RhIII centres was achieved to form metallacalix[4]arene-type clusters. The thyminate(2-) bridged two RhIII and the third metal ion with a μ3-1κN1:2κ2N3,O2:3κO2 mode in the Na+ and Ca2+ complexes, while in the Ln3+ analogues it exhibited a different bridging mode, μ3-1κN1:2κ2N3,O4:3κO2.",

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T1 - Thyminate(2-)-bridged cyclic tetranuclear rhodium(III) complexes formed by a template of a sodium, calcium or lanthanoid ion

AU - Kashima, Ayana

AU - Sakate, Mika

AU - Ota, Hiromi

AU - Fuyuhiro, Akira

AU - Sunatsuki, Yukinari

AU - Suzuki, Takayoshi

PY - 2015/2/4

Y1 - 2015/2/4

N2 - In the thyminate(2-)-bridged tetranuclear Cp∗RhIII complexes incorporating a Na+, Ca2+ or Ln3+ cation, homochiral aggregation of four RhIII centres was achieved to form metallacalix[4]arene-type clusters. The thyminate(2-) bridged two RhIII and the third metal ion with a μ3-1κN1:2κ2N3,O2:3κO2 mode in the Na+ and Ca2+ complexes, while in the Ln3+ analogues it exhibited a different bridging mode, μ3-1κN1:2κ2N3,O4:3κO2.

AB - In the thyminate(2-)-bridged tetranuclear Cp∗RhIII complexes incorporating a Na+, Ca2+ or Ln3+ cation, homochiral aggregation of four RhIII centres was achieved to form metallacalix[4]arene-type clusters. The thyminate(2-) bridged two RhIII and the third metal ion with a μ3-1κN1:2κ2N3,O2:3κO2 mode in the Na+ and Ca2+ complexes, while in the Ln3+ analogues it exhibited a different bridging mode, μ3-1κN1:2κ2N3,O4:3κO2.

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