Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications

Masahito Murai, Hiroyuki Maekawa, Shino Hamao, Yoshihiro Kubozono, David Roy, Kazuhiko Takai

研究成果査読

21 被引用数 (Scopus)

抄録

Novel [6]phenacenes (fulminenes) with two long alkyl chains at the axis positions were synthesized. This short synthesis comprises the following three steps: (1) ruthenium-catalyzed direct C-H bond arylation; (2) conversion of directing groups by Wittig reaction; and (3) bismuth- or gold-catalyzed cyclization of vinyl ether. Organic field-effect transistor devices fabricated with a thin film of 3,11-di(tetradecyl)fulminene exhibited typical p-channel normally-off properties.

本文言語English
ページ(範囲)708-711
ページ数4
ジャーナルOrganic Letters
17
3
DOI
出版ステータスPublished - 2月 6 2015

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

フィンガープリント

「Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル