Viologen as catalytic organic reductant: Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

Manabu Kuroboshi; Takuya Shiba; Hideo Tanaka

doi:10.1016/j.tetlet.2013.04.127

Viologen as catalytic organic reductant: Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

Manabu Kuroboshi
, Takuya Shiba
, Hideo Tanaka

研究成果 › 査読

21 被引用数 (Scopus)

抄録

Viologen can be used as an in situ recyclable organic reductant. Pd-catalyzed electrochemical reductive coupling of aryl bromides was performed by using a catalytic amount of viologen to afford the corresponding biaryls in good to moderate yields.

本文言語	English
ページ（範囲）	3666-3668
ページ数	3
ジャーナル	Tetrahedron Letters
巻	54
号	28
DOI	https://doi.org/10.1016/j.tetlet.2013.04.127
出版ステータス	Published - 7月 10 2013

ASJC Scopus subject areas

生化学
創薬
有機化学

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引用スタイル

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abstract = "Viologen can be used as an in situ recyclable organic reductant. Pd-catalyzed electrochemical reductive coupling of aryl bromides was performed by using a catalytic amount of viologen to afford the corresponding biaryls in good to moderate yields.",

keywords = "Electroreduction, Mediatory system, Pd catalyst, Reductive coupling of aryl halide, Viologen",

author = "Manabu Kuroboshi and Takuya Shiba and Hideo Tanaka",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number 22550102 and Shorai Foundation for Science and Technology . The authors also thank Mrs. Atsuko Takamaru, Okayama University, for elemental analyses. ",

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AU - Shiba, Takuya

AU - Tanaka, Hideo

N1 - Funding Information: This work was supported by JSPS KAKENHI Grant Number 22550102 and Shorai Foundation for Science and Technology . The authors also thank Mrs. Atsuko Takamaru, Okayama University, for elemental analyses.

PY - 2013/7/10

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AB - Viologen can be used as an in situ recyclable organic reductant. Pd-catalyzed electrochemical reductive coupling of aryl bromides was performed by using a catalytic amount of viologen to afford the corresponding biaryls in good to moderate yields.

KW - Electroreduction

KW - Mediatory system

KW - Pd catalyst

KW - Reductive coupling of aryl halide

KW - Viologen

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