抄録
The reactions of the cis- and trans-2-butenes photosensitized by Zn(3P1) have been studied. The main reaction was cis-trans isomerization. The photostationary [trans]/[cis] ratio was 1.5/1.0 and did not vary with pressure. This ratio is different from those obtained in the mercury- and cadmium-photosensitized reactions. The isomerization of 2-butenes photosensitized by Zn(3P1) could not be explained in terms of the simple mechanism proposed for the mercury- and cadmium-photosensitized reaction of 2-butenes. Possible mechanisms are discussed.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 55-64 |
| ページ数 | 10 |
| ジャーナル | Journal of Photochemistry |
| 巻 | 38 |
| 号 | C |
| DOI | |
| 出版ステータス | Published - 6月 1987 |